Correction: i think i was using a pre SP1 disc. Large hdd support must've come in with SP1. It was yonks ago that i was reading about it (hence the haziness), but I think XP pro pre-SP1 was capped at 137gb or 167gb. The hdd in question is 200gig. Will do some googling when i get home, but the important thing (to me) is that I've upgraded Windows to SP2 and ALL the files are automagically uncorrupted.
Found the SP2 disc eventually, so all's well. (prolly sounds silly but I was trying to avoid d/ling big windows updates, cos my d/l quota is just about maxed out and i hate being capped at 56k).
Aaanyways...I intend to destroy that old install disc asap.
First item on the to-do list tonight: research raid.
Thanks for your help folks.