You notice the sliders are in 3db increments? You can get finer control using them in combination with volume envelopes.
The sliders are in 1db by default, but you can do fine tuning by double clicking on them.
How much of each should I try to mix in and is there a better way to accomplish this than with the slider on the left side of the individual audios?
In short, no. The bright side is that slider is real-time so hit play and then slowly increase one of the two sources and you should hear it grow more prominent in the mix. The downside is you cant say "I want an absolute volume of X, give me percentages of each source" and let it limit itself that way. Never hindered me, just had to think about it a little.
I recorded the first show in 16/44 but the last 2 I have done in 24/48, I'm sure there is something that I need to do to convert the shows but I'm not sure what. I think this is called dithering but I'm probably mistaken.
You'll need to setup dithering anyway, since all of your mixing is taking place in 32bit (default).
Preferences > Quality > and then set the dither options there. If you are using a plugin (VST or otherwise) then set your dither to NONE otherwise if you are using Audacity's dither, set it here. Be warned, when you set it to dither here, it dithers *all the time* during export, not just when you are using stuff that is greater then 16bit. Most people don't care, but if you are using Audacity for just tracking or something else that is not audio destructive, then keep that in mind. I recommend rendering the two track mix down before exporting so you can see if there is any clipping, but technically it's not required if you set it up correctly.
Its a quirky editor, but the price is right, and it has some features that I can't find in others.