With the microphones you have, you should definitely be able to record and process "double M/S" without Schoeps' special mounting hardware or other outboard accessories. In Europe there is considerably more surround sound recording the professional level than there is here in the States. The "double M/S" system was originally conceived at Schoeps as a way to produce 5.0 or 5.1 surround sound, and that's what the accessories are mainly for (such as the transformer box with the three inputs and the five outputs).
The software plug-in is based on the specific characteristics of the MK 4V and MK 8 capsules (or the corresponding CCM-series microphones) so the results won't match what the software controls are showing you if you use (say) an MK 21 as the front capsule, but you can still futz around and choose settings by ear, and you might find settings that you like, who knows? It's just not the way the system was designed, and it probably won't work as well as if you Read and Follow the Directions on the Label. But sometimes the destination is the journey, and you won't necessarily break anything by experimenting.
For me, and I suspect most other Americans here, the main attraction of this approach is having a better way to tailor your two-channel stereo recordings "after the fact" than you get with regular M/S. With regular M/S you really have only one variable that you control: the relative proportion of S versus M signal. Add more S and the stereo image widens, but the amount of reverberance also increases. That limits your options because when you widen out, you probably want a bit more direct sound (more detail) rather than less. As a result, whenever I've recorded M/S I've never felt that there was more than one plausible compromise setting.
Double M/S, on the other hand, especially via the software plug-in, gives you two independent variables that can be chosen "after the fact": stereo image width AND reverberance (separately). That's neat.
--best regards